Adsorption Properties for La(III), Ce(III), and Y(III) with Poly(6-acryloylamino-hexyl hydroxamic acid) Resin.

Abstract

Using polyacrylic resin followed by the substitution reaction with 6-aminohexyl hydroxamic acid, poly(6-acryloylamino-hexyl hydroxamic acid) resin (PAMHA) was successfully synthesized. PAMHA, a spherical resin with the particle size of 0.4 mm, is a novel polyamide hydroxamic acid chelating resin containing acylamino and hydroxamic acid functional groups. A series of influences (pH, contact time, temperature, and the initial concentrations of rare earth ions) were investigated to determine the adsorption properties. The adsorption capacity for La(III), Ce(III), and Y(III) ions were 1.030, 0.962, and 1.450 mmol·g−1, respectively. Thermodynamic and kinetic studies were also carried out to show that the uptake of rare earth ions onto PAMHA fitted well the pseudo-second-order model and Langmuir isotherm, and the adsorption process was spontaneous endothermic. In addition, desorption of rare earth ions was achieved by using 2 mol·L−1 HNO3 and desorption efficiencies for La(III), Ce(III), and Y(III) ions were 98.4, 99.1, and 98.8%, respectively. Properties of PAMHA resin were characterized by scanning electron microscope (SEM), Fourier transform infrared spectrometry (FTIR), and X-ray photoelectron spectrometer (XPS). The results showed that there was coordination between the rare earth ions with PAMHA and rare metal ions were chemically adsorbed on the surface of the PAMHA.