Abstract
The adsorption of thiosemicarbazide (TSC) on cathodically polarized iron is studied. The adsorption follows both the Flory-Huggins and the Bockris-Swinkels isotherms with a standard free energy of adsorption of about 37 kJ mol −1. Four water molecules are displaced by each adsorbing TSC molecule. This is explained on the basis of molecular models.
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