Abstract
AbstractThe adsorption of thiosemicarbazide (TSC) on cathodically polarised copper is studied. The adsorption follows the Flory‐Huggins and the Bockris‐Swinkels isotherms with a standard free energy of adsorption of about 20kJmol−1. Four water molecules are displaced by each adsorbing TSC molecule. This is explained on the basis of molecular models.
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