Abstract
The interaction of methanol, dimethyl ether, diethyl ether and ethanoic acid with H-ZSM-5 and silicalite surfaces has been examined by determining the differential molar enthalpy and entropy of adsorption at 323.16 K. The results complement spectroscopic studies by providing further evidence for the formation of clusters around protonated adsorbed methanol molecules, and have confirmed the very strong interaction of both ethers with the zeolite Bronsted acid sites. Adsorption of ethanoic acid on the zeolite was strongly influenced by geometric restrictions on its possible orientation inside the pore system.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Journal of the Chemical Society, Faraday Transactions
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
