Adsorption of Fragrance Capsules onto Cellulose Nano- and Micro-Cellulose Fibers in Presence of Guar Biopolymers

Abstract

Fabric softeners are formulated to enhance textile softness and impart a pleasant scent. One of the most efficient technologies for controlled fragrance delivery onto fabrics involves encapsulating scent molecules in polymer capsules. Here, we investigate the adsorption of anionic fragrance capsules on cotton fabrics with the goal of reducing the reliance on palm-oil-derived surfactants. First, we employ 200 nm cellulose nanocrystals (CNC) as a reliable model for cotton fibers. CNC enables us to explore interactions among various softener components, including surfactants, guar biopolymers, and fragrances, using physical chemistry techniques applied to bulk dispersions. The primary objective is to elucidate the role of surfactant vesicles, the primary ingredient in textile conditioners, in the association between fragrance capsules and cotton. Secondly, we examine the influence of biopolymers present in a newly developed environmentally friendly softener on this association. Our findings demonstrate that anionic fragrance capsules are deposited onto cotton microfibers in the presence of either cationic surfactants or guar biopolymers, driven by electrostatic interactions. Scanning electron microscopy confirms capsule adsorption on textile fibers when these cationic ingredients are present. Understanding the interaction mechanisms between fragrance capsules and cotton fabrics, as well as the roles played by other softener components, can facilitate the design of more efficient and sustainable formulations.