Abstract
A comprehensive understanding of the interactions between organic molecules and a metal oxide surface is essential for an efficient surface modification and the formation of organic–inorganic hybrids with technological applications ranging from heterogeneous catalysis and biomedical templates up to functional nanoporous matrices. In this work, first-principles calculations supported by experiments are used to provide the microstructural characteristics of (101̄0) surfaces of zinc oxide single crystals modified by azide terminated hydrocarbons, which graft on the oxide through a thiol group. On the computational side, we evaluate the specific interactions between the surface and the molecules with the chemical formula N3(CH2)nSH, with n = 1, 3, 6, 9. We demonstrate that the molecules chemisorb on the bridge site of ZnO(101̄0). Upon adsorption, the N3(CH2)nSH molecules break the neutral (Znδ+–Oδ−) dimers on ZnO(101̄0) resulting in a structural distortion of the ZnO(101̄0) substrate. The energy decomposition analysis revealed that such structure distortion favors the adsorption of the molecules on the surface leading to a strong correlation between the surface distortion energy and the interaction energy of the molecule. An azide-terminated thiol with three methylene groups in the hydrocarbon chain N3(CH2)3SH was synthesized, and the assembly of this linker on ZnO surfaces was confirmed through atomic force microscopy. The bonding to the inorganic surface was examined via X-ray photoelectron spectroscopy (XPS). Clear signatures of the organic components on the oxide substrates were observed underlying the successful realization of thiol-grafting on the metal oxide. Temperature-dependent and angle-resolved XPS were applied to examine the thermal stability and to determine the thickness of the grafted SAMs, respectively. We discuss the high potential of our hybrid materials in providing further functionalities towards heterocatalysis and medical applications.
Highlights
Metal oxides, like AgO, Al2O3, ZrO2, ZnO, TiO2 etc. are abundant in every day life and have been used for diverse applications
A comprehensive understanding of the interactions between organic molecules and a metal oxide surface is essential for an efficient surface modification and the formation of organic–inorganic hybrids with technological applications ranging from heterogeneous catalysis and biomedical templates up to functional nanoporous matrices
The energy decomposition analysis revealed that such structure distortion favors the adsorption of the molecules on the surface leading to a strong correlation between the surface distortion energy and the interaction energy of the molecule
Summary
Like AgO, Al2O3, ZrO2, ZnO, TiO2 etc. are abundant in every day life and have been used for diverse applications. Surface functionalization can impart enhanced electronic, photocatalytic and luminescence properties.[20,21,22] In addition, the presence of organic molecules on the oxide surface can act as protective layer against corrosion.[23] Speci cally, ZnO (1010) due to its large speci c surface area as in two-dimensional materials has a large affinity towards molecular adsorption It could be used in sensing and catalysis applications for the adsorption of gas molecules, organic linkers, and reaction intermediates.[24,25,26,27,28] An important approach that has been used to functionalize ZnO surfaces is the incorporation of 5466 | RSC Adv., 2021, 11, 5466–5478
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.