Abstract
In this work, a cross-linked porous polyimide (PI) network, fabricated from an “elongated” dianhydride and melamine, was synthesized by polycondensation and thermal dehydration. The as-prepared PI revealed an excellent adsorption performance and removal for acid orange 10 (AO-10) from aqueous solution. The adsorption quantity can reach 599 mg/g when the initial concentration is 500 mg/L with the temperature 298 K and pH value of 3. The maximum desorption ratio can be 38.9%. It is expected that the adsorption quantity and desorption ratio can be optimally improved by changing the length of PI monomer, indicating the cross-linked porous PI network is not only served effectively in sewage treatment but also recycled. Pseudo-2nd-order kinetic model and Langmuir isotherm are better fitted with the kinetic data and the adsorption equilibrium data respectively.
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