Abstract

The adsorption behavior of Cr(Ⅳ) on Mg-Al hydrotalcite compounds(Mg-Al HTlc) was investigated in the metal-organic pollutant system of Cr(Ⅵ) and p-cresol.The results suggest that in the adsorption of Cr(Ⅵ) on HTlc is in the pseudo-second-order reaction and follows Langmuir isothermal adsorption equation;p-cresol can reduce the adsorption velocity but can increase the adsorption capacity of Mg-Al HTlc to adsorb Cr(Ⅵ) from water.Cr(Ⅵ) and p-cresol exhibit a competitive effect.On the one hand,the competitive effect is dependent to the concentration ratio of p-cresol to Cr(Ⅵ),the adsorption capacity of Mg-Al HTlc toward Cr(Ⅵ) can be increased by decreasing the pH value due to the adsorption of p-cresol on HTlc.The competitive ability of p-cresol decreases relatively with the increase of Cr(Ⅵ) concentration and the removal rate of Cr(Ⅵ) increases significantly when the mass concentration ratio of Cr(Ⅵ) to p-cresol is larger than 3.In addition,the adsorption capacity decreases with increasing temperature.

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