Adsorption and mineral trapping dominate CO2 storage in coal systems

Abstract

High-CO2 coal seams occur in many sedimentary basins world-wide and provide natural analogues of the processes likely to occur as a result of CO2 injection and storage in coal systems. CO2 is stored in coal predominantly as adsorbed molecules on micropore surfaces (adsorption trapping) that allow higher densities and greater volumes of CO2 at shallower depths than in sandstone and carbonate reservoirs. In the longer term CO2 will dissolve in formation water and react with minerals in the host formation (solubility/ionic trapping) and may be precipitated as carbonate minerals (mineral trapping). A recent study suggests that solubility trapping is the predominant CO2 sink in natural gas fields (Gilfillan et al., 2009), whereas our natural analogue studies in the Bowen and Gunnedah Basins, eastern Australia, indicate that CO2 has been stored in coal and sandstone formations since the Mesozoic through a combination of adsorption and mineral carbonation reactions. These differences reflect the different mineralogies and hydrogeology of the CO2-rich natural gas fields studied by Gilfillan et al. (2009) and coal systems. Our work shows that natural analogue studies of sites that have stored CO2 over geological time scales are essential to determine the mechanisms of CO2 storage and the level of characterisation required for storage site equivalents. (C) 2011 Published by Elsevier Ltd.