Abstract
<p>The textile industry in Indonesia is growing rapidly, this is confirmed by data from the Badan Pusat Statistik (BPS) which shows that the production of the clothing industry has experienced a significant growth of 15.29 percent in 2019. The use of textile dyes will cause waste problems in the environment. So we need natural dyes as a safer and environmentally friendly alternative. The purpose of this study was to obtain data analysis and to determine the adsorption equilibrium value of the natural dye solution of mangrove <em>Rhizophora stylosa</em> and tingi bark with variations in the amount of dyeing in primisima cloth by comparing it with the Langmuir and Freundlich equations and knowing the role of tunjung and alum in the process of fixing dyes into cloth. This study used a solid-liquid extraction method and then tested by spectrophotometry to obtain initial concentration data. Next, pour the dye that has been tested for its tannin content into a measuring cup and insert the cloth as a medium for mass transfer of tannins from liquid to solid. Samples were taken for each dyeing and tested for tannin content by spectrophotometry and the Ca value was obtained. Isotherm pattern testing. The adsorption test for the absorption process of tannins in natural dyes by cloth was carried out by calculating using the Langmuir and Freundlich equation. Furthermore, the cloth that has been dyed is fixed by tunjung and alum.The most suitable determination of the adsorption capacity of the cloth against natural dyes <em>Rhizopora stylosa</em> and tingi bark is by using the Freundlich adsorption equation compared to the Langmuir equation. This is evidenced by the error value of the Freundlich equation is smaller than the Langmuir equation by showing the value of R<sup>2</sup> which is close to number 1. The constant value of the Langmuir equation tingi bark for three times of dyeing obtained the b value is 0.2338 mg/gr and the k value is 0.00517 L/gr. For five of dyeing, the b value is 0.10817 mg/gr and the k value is 0.00421 L/gr. For the seven times of dyeing, the b value is 0.0670 mg/gr and the k value is 0.003899 L/gr. Whereas in the Freundlich equation for tingi bark for three times of dyeing, the n value is 0.4312 mg/g and the k value is 0.36374 x 10<sup>3</sup> L/gr. For five of dyeing, the n value is 0.30114 mg/g and the k value is 0.99586 x 10<sup>5</sup> L/g. For seven of dyeing, the n value is 0.2424 mg/g and the k value is 0.9354 x 10<sup>7</sup> L/g. The constant value of the Langmuir <em>Rhizopora stylosa</em> equation for three times of dyeing, the b value is 0.15635 mg / gr and the k value is 0.005224 L/gr. For five of dyeing, the b value is 0.08141 mg/gr and the k value is 0.004415 L/gr. For the seven of dyeing, the b value is 0.04909 mg/gr and the k value is 0.00408 L/gr. Whereas in the Freundlich equation for <em>Rhizopora stylosa</em> for three times of dyeing, the n value is 0.3862 mg/g and the k value is 0.1090 x 10<sup>4</sup> L/g. For five of dyeing, the n value is 0.2733 mg/g and the k value is 0.4355 x 10<sup>6</sup> L/g. For seven of dyeing, the n value is 0.2126 mg/g and the k value is 0.1545 x 10<sup>9</sup> L/g. It can be concluded that the more dyeing, the less the absorbency of the cloth on tannins. The color change of fixation the cloth in the dyeing of <em>Rhizopora stylosa</em> extract with tunjung is from brown to grayish brown, while with alum from brown to dark brown. The color change of fixation the cloth in the dyeing of tingi bark extract with alum is from brown to black, while with alum from brown to dark brown.</p>@font-face {font-family:"Cambria Math"; panose-1:2 4 5 3 5 4 6 3 2 4; mso-font-charset:0; mso-generic-font-family:roman; mso-font-pitch:variable; mso-font-signature:-536869121 1107305727 33554432 0 415 0;}@font-face {font-family:Garamond; panose-1:2 2 4 4 3 3 1 1 8 3; mso-font-charset:0; mso-generic-font-family:roman; mso-font-pitch:variable; mso-font-signature:647 2 0 0 159 0;}p.MsoNormal, li.MsoNormal, div.MsoNormal {mso-style-unhide:no; mso-style-qformat:yes; mso-style-parent:""; margin-top:0cm; margin-right:0cm; margin-bottom:0cm; margin-left:.5pt; text-align:justify; text-justify:inter-ideograph; text-indent:-.5pt; line-height:103%; mso-pagination:widow-orphan; font-size:11.0pt; font-family:"Garamond",serif; mso-fareast-font-family:Garamond; mso-bidi-font-family:Garamond; color:black; mso-ansi-language:EN-US; mso-fareast-language:EN-US;}.MsoChpDefault {mso-style-type:export-only; mso-default-props:yes; font-size:11.0pt; mso-ansi-font-size:11.0pt; mso-bidi-font-size:11.0pt; font-family:"Calibri",sans-serif; mso-ascii-font-family:Calibri; mso-ascii-theme-font:minor-latin; mso-fareast-font-family:DengXian; mso-fareast-theme-font:minor-fareast; mso-hansi-font-family:Calibri; mso-hansi-theme-font:minor-latin; mso-bidi-font-family:"Times New Roman"; mso-bidi-theme-font:minor-bidi; mso-ansi-language:EN-US; mso-fareast-language:EN-US;}.MsoPapDefault {mso-style-type:export-only; margin-bottom:8.0pt; line-height:107%;}div.WordSection1 {page:WordSection1;}
Highlights
Industri di Indonesia mengalami perkembangan yang sangat pesat khususnya di bidang industri tekstil, hal tersebut diperkuat dari data Badan Pusat Statistik (BPS) yang menunjukkan bahwa produksi industri pakaian mengalami pertumbuhan signifikan sebesar 15,29 persen pada tahun 2019 [8]
this is confirmed by Badan Pusat Statistik
which shows that the production of the clothing industries have a significant growth
Summary
Industri di Indonesia mengalami perkembangan yang sangat pesat khususnya di bidang industri tekstil, hal tersebut diperkuat dari data Badan Pusat Statistik (BPS) yang menunjukkan bahwa produksi industri pakaian mengalami pertumbuhan signifikan sebesar 15,29 persen pada tahun 2019 [8]. Bahan lainnya yang juga dapat digunakan sebagai bahan pewarna alami pengganti pewarna sintetis selain buah mangrove yaitu kulit kayu tingi. Buah mangrove dan kulit kayu tingi dikeringkan terlebih dahulu dengan cara dijemur hingga benar-benar kering ditandai dengan perubahan warna dari hijau menjadi hitam. Langkah kedua yaitu mengekstraksi zat warna dari mangrove Rhizopora Stylosa dan kulit kayu tingi. Kemudian larutan ditambahkan air sebanyak 10 liter dan diaduk hingga homogen, maka kain primisima siap untuk mordanting dengan cara mencelupkan kain ke dalam larutan tersebut selama 10 menit. Analisis Hasil Hasil ekstraksi dari buah mangrove jenis Rhizophora stylosa dan kulit kayu tingi dianalisis kadar tanin untuk menentukan konstanta kesetimbangan adsorbsi. Selanjutnya menentukan konstanta kesetimbangan adsorbsi dengan menggunakan persamaan Langmuir dan Freundlich yang telah disusun, kemudian dilakukan perhitungan secara numeris menggunakan program Microsoft Excel.
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