Abstract
We use the adiabatic theory in the complex plane of internuclear distance to calculate the Rydberg-state broadening cross sections in the ambient alkali-metal gases. We have found that the imaginary parts of the branch points between the relevant energy curves have an oscillatory structure that is projected into a similar structure in the broadening cross section. The results of the distorted-wave diabatic perturbation theory and the present theory are in excellent agreement for the principal quantum numbers of the Rydberg atoms n<30. Unlike the diabatic perturbation theory, the adiabatic approach does not merge with the impulse approximation and fails for higher n
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More From: Physical review. A, Atomic, molecular, and optical physics
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