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https://doi.org/10.1021/acs.inorgchem.1c01483
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Cite Journal: Inorganic Chemistry |  Publication Date: Aug 12, 2021 |
 Citations: 16 |
Affiliation: Babeș-Bolyai University, Ivanovo State University
Aquacobalamin binds hydrogen peroxide reversibly to form a cobalt(III) hydroperoxo adduct with a 0.25 mM dissociation constant, as evidenced by UV-vis absorption spectroscopy and corroborated by NMR, Raman spectroscopy, stopped-flow UV-vis measurements, and density functional theory calculations.
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