Abstract
Abstract The synthesis and spectroscopic properties of some new acyls of Ni(II) of formula Ni(COR)(S2 CNR′2)(PMe3) (R=Me3- SiCH2, Me2PhCCH2; R′=Me, Et, i-Pr) are described. Infrared and 1Hnmr studies show a square planar structure for the complexes with a bidentate dithiocarbamate ligand. The new acyls undergo dynamical behaviour in solution and participate in carbon monoxide exchange reactions with NiRCI(PMe3)2 complexes to give NiR-(S2CNR′2)(PMe3) and Ni(COR)CI(PMe3)2.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
