Abstract

Plasma-catalysis has attracted great attentions in environmental/energy-related fields, but the synergetic mechanism still suffers intractable defects. Key issues are that what kind of catalysts are applicable for plasma system, how are they activated in plasma, and how to characterize them in plasma. This review systematically gives a comprehensive summarization of the selection of catalysts and its activation mechanism in plasma, based on the character of plasma, including physical effects containing the enhancement of discharge intensity and adsorption of reactants, and the utilization of plasma-generated active species such as·O, heat, O3, ultraviolet light and e* . Focus is given to the illumination of the activation mechanisms of catalysts when placed in plasma zone. Subsequently, the novel characterization techniques for catalysts, which may associate properties to performance, are critically overviewed. The challenges and opportunities for the activation and characterizations of catalysts are proposed, and future perspectives are suggested about where the efforts should be made. It is expected that a bridge between catalysts design and character of plasma can be built to shed light on the synergetic mechanism for plasma-catalysis and design of new plasma-catalysis systems.

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