Abstract
We demonstrate time-resolved temperature measurements in shock-heated mixtures of carbon monoxide over a temperature range of 1000-1800K for two pressure ranges, 2.0-2.9atm and 7.6-10.7atm, at rates up to 250kHz using a single acousto-optically modulated quantum cascade laser with mid-infrared output spanning from 1975 to 2260 cm-1. Measured temperatures were in excellent agreement with values determined by ideal shock relations, and the temperature profile after the passage of the reflected shock wave was found to be well-modeled by an isentropic compression assumption. Temperature measurements made with this setup are largely immune to effects of emissions and beam steering, making the diagnostic system well-suited for studying high-temperature gas-phase reactions of energetic materials such as octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine and hexahydro-1,3,5-trinitro-1,3,5-triazine.
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