Abstract
Broadband acoustical spectrometry data for three types of unimolecular reactions in liquids are discussed: outer sphere complex - contact ion pair isomerization, monosaccharide chair-chair conformational changes, and propyl formate structural isomerization. The temperature dependent relaxation times and amplitudes are discussed in terms of a thermally activated relaxation scheme to yield the thermodynamic and kinetic parameters of the elementary chemical equilibrium. Limitations in the determination of these parameters are indicated.
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