Abstract
The observed experimental parameters such as density ( �), viscosity ( �) and ultrasonic velocity (U) of ternary liquid mixtures of primary alkanols such as 1-propanol, 1-butanol, 1-pentanol and 1-hexanol with N-N dimethylfomamide (DMF) in acetophenone at 303.15 K were determined. The observed experimental data have been utilized to evaluate some of the thermo acoustical parameters and also their excess values such as adiabatic compressibility ( � E ), intermolecular free length (L f E ), free volume (V f E ), internal pressure ( �i E ), Gibb's energy ( �G E ) and viscosity ( � E ). Our present investigation observes that the interaction between DMF (Proton acceptor) and 1-alkanols is due to hydrogen bonding. There seems to be a dissociation of associated structure of 1-alkanols and decrease in interaction (hydrogen bonding) between acetophenone and 1-alkanols on further addition of DMF. It is also noticed that on further addition of DMF leads to subsequent decrease in interaction between ketone (acetophenone) and 1-alkanols as well as between DMF and 1-alkanol, which eventually resulting in existence of weak molecular interactions in the present system of liquid mixtures.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
