Abstract

For the first time, the necessity to thermally pre-treat ubiquitously used PET substrates for printed electronics, to improve dimensional stability during manufacturing, is clearly defined. The experimental results have proven this phenomenon for both roll-to-roll (R2R) and sheet-to-sheet (S2S) processing of printed electronics. The next generation of electronics manufacturing has pushed the boundaries for low-cost, flexible, printed, and mass produced electronic components and systems. A driving force, and enabling production method, are the R2R printing presses. However, to produce electronics with increasing complexity and high yield in volume production, one must have a highly accurate process. In this article, R2R processing accuracy of printed electronics is evaluated from the point of dimensional accuracy of the flexible polyester substrate (DuPont Teijin Films’ PET Melinex ST504 with and without indium tin oxide, Melinex ST506, and Melinex PCS), precision of printing, and accuracy of layer-to-layer registration with stages that involve tension and elevated temperatures. This study has confirmed that dimensional changes during R2R processing will occur only in the first processing stage and that if a thermal pre-treatment run for the substrate is made—at identical temperature and tension of the processing stage—there is improved stability originating from a new-level strain in the crystalline PET film structure and freezing it in at the tensions and temperatures it is exposed to (i.e. 1400 μm machine direction stretching reduced to 8 μm). Furthermore, it is explained how the dimensional accuracy can be improved and reproducibly maintained in multilayer printing of electronics devices such as organic photovoltaics (OPV). These devices provide a valuable baseline of how the layer-to-layer alignment accuracy plays a crucial role in fully printed electronics devices, which lessons can be applied in all aspects of this field including hybrid systems and system fabrication involving multiple processing methods.

Highlights

  • Electronics design and manufacturing have evolved significantly over the past decades and advanced with opportunities provided by printed electronics enabling technologies

  • We present the R2R and S2S processing accuracy for printed electronics by examining the accuracy of the polyethylene terephthalate (PET) substrate, printing techniques and layerto-layer registration

  • The dimensional accuracy of Heat stabilized PET (HS-PET) substrates was evaluated by exposing the substrate materials to the heat and tension of a R2R cycle, and measuring the substrate machine direction (MD) dimensions before and after the processing at ambient temperature and zero tension

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Summary

Introduction

Electronics design and manufacturing have evolved significantly over the past decades and advanced with opportunities provided by printed electronics enabling technologies. There is a strong need for high yield and accurate R2R processes as they can be used in the volume manufacturing of various multilayer devices such as solar cells, supercapacitors and batteries, transistors and flexible hybrid electronics (FHE), and even double-sided structures [1,2,3,4,5,6,7,8,9,10,11]. Layer-to-layer alignment accuracy sets a key requirement for printed electronics applications where any deviations in the positioning of the layers impair the device performance and increases performance variations among devices. This registration accuracy defines the precision of the printed, multilayered pattern. The registration demands in printed electronics are much stricter than in conventional printing where

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