Abstract

The design and synthesis of mainchain chromophore polymers in a syndioregic (head-to-head) configuration is described. Polymers were designed for both electric-field poling and Langmuir-Blodgett-Kuhn (LBK) deposition. LBK deposition gives intrinsically polar films (no E-field poling) as evidenced by nonlinear optical (χ (2)) properties.

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