Abstract
A gaseous reactant is absorbed in a liquid with a positive heat of absorption. It reacts with the liquid by an exothermic, irreversible first order reaction. Analysis of a CSTR for this process has shown that up to 5 steady state solutions may exist even though the system appears to be quite simple with only one reaction. The existence of an extraordinary large number of steady state solutions is explained by the coupling between absorption and reaction: A low temperature gives no reaction, a high temperature prevents absorption of the gas and hence leads to mass transfer control of the reaction, while an intermediate temperature may permit operation at a third (stable) steady state. In between the stable steady states one finds (as us two unstable steady states. We extend the analysis of the CSTR to the distributed system of a falling film reactor, and we treat both the transient situation in the entrance part An eigenanalysis of the steady states shows that temperature rise across the gas film may lead to 3 stable steady states even if an isothermal model is
Published Version
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