Abstract
Experimental infinite dilution activity coefficient data, gas-to-liquid partition coefficient data, and solubility data have been combined from the published literature for neutral organic molecules and inert gases dissolved in anhydrous acetic acid. The compiled experimental data were transformed into molar solubility ratios, water-to-acetic acid (P) and gas-to-acetic acid (K) using standard thermodynamic relationships. The derived Abraham model correlations described the observed solubility and partition coefficient data of neutral organic compounds to within 0.18 log units (or less). Our analysis further showed that acetic acid solvent has considerable hydrogen-bond acidity, in agreement with the proposed linear structure for the solvent, and in terms of solubility related properties is not an unusual solvent at all.
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