Abstract
In this work, we present a thorough study of the optical properties of the layered orthorhombic compound ${\text{In}}_{4}{\text{Se}}_{3}$. The dielectric function---real and imaginary parts, the complex refraction index, the reflectivity, the absorption coefficient, and the conductivity of ${\text{In}}_{4}{\text{Se}}_{3}$ were calculated with the inclusion of the spin-orbit interaction, using an ab initio FP-LAPW method based on DFT. Also, generalized ellipsometry was employed for more precise measurement of the anisotropic dielectric functions for polarization along crystal $a$, $b$, and $c$ axes of orthorhombic absorbing ${\text{In}}_{4}{\text{Se}}_{3}$ single crystals cut approximately parallel to (100) at photon energies from 0.76 to 3.1 eV. Our experimental results show a good agreement with our calculations. We discuss the location and nature of the main optical peaks appearing in the spectra. The obtained optical functions display a rather anisotropic behavior, mainly in the infrared-visible region. Our results seem to be predictive to a high extension, given the scarce experimental information about its optical properties.
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