Abstract
Cerium(III) nitride chloride, Ce2NCl3, contains trans-edge connected [NCe4]9+ tetrahedra (222 symmetry) forming chains parallel to the c axis that are separated by Cl− anions. The Ce3+ cations (..m symmetry) are each surrounded by two N3− and six Cl− anions in a bicapped trigonal prismatic coordination geometry (CN = 8).
Highlights
Cerium(III) nitride chloride, Ce2NCl3, contains trans-edge connected [NCe4]9+ tetrahedra (222 symmetry) forming chains parallel to the c axis that are separated by Cl anions
−y, −z+1/2; (viii) −x, y, z−1/2; (ix) −x, y, z+1/2; (x) x, −y+1, −z+1/2; (xi) −x+1/2, y+1/2, z
Summary
Institut für Anorganische Chemie, Universität Stuttgart, Pfaffenwaldring 55, 70569. R factor = 0.035; wR factor = 0.061; data-to-parameter ratio = 19.2. Cerium(III) nitride chloride, Ce2NCl3, contains trans-edge connected [NCe4]9+ tetrahedra (222 symmetry) forming chains parallel to the c axis that are separated by Cl anions. The. and six Cl anions in a bicapped trigonal prismatic coordination geometry (CN = 8)
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