Abstract
AbstractThe new hybrid inorganic–organic polymer [MoO2Cl2(H2O)2]·(H2dipy‐pra)Cl2 (1), where dipy‐pra = 1,3‐bis(4‐pyridyl)propane, has been synthesized and crystallographically characterized. MoO2Cl2(H2O)2 and the [H2dipy‐pra]2+ cation are cross‐linked by Mo–H2O···Cl and H2dipy‐pra···Cl hydrogen bonds to form a two‐dimensional layer structure. Complex 1 is an efficient catalyst, with H2O2 as the oxygen‐source oxidant and NaHCO3 as the cocatalyst, in the epoxidation of olefinic compounds under ambient conditions.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)
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