A three-dimensional ZnII coordination polymer constructed from 1,1'-biphenyl-2,2',4,4'-tetracarboxylate and 1,4-bis(1H-imidazol-1-yl)benzene ligands exhibiting photoluminescence.

Abstract

Ligands based on polycarboxylic acids are excellent building blocks for the construction of coordination polymers; they may bind to a variety of metal ions and form clusters, as well as extended chain or network structures. Among these building blocks, biphenyltetracarboxylic acids (H4bpta) with C2 symmetry have recently attracted attention because of their variable bridging and multidentate chelating modes. The new luminescent three-dimensional coordination polymer poly[(μ5-1,1'-biphenyl-2,2',4,4'-tetracarboxylato)bis[μ2-1,4-bis(1H-imidazol-1-yl)benzene]dizinc(II)], [Zn2(C16H6O8)(C12H10N4)]n, was synthesized solvothermally and characterized by single-crystal X-ray diffraction, elemental analysis and IR spectroscopy. The crystal structure contains two crystallographically independent ZnII cations. Both metal cations are located on twofold axes and display distorted tetrahedral coordination geometries. Neighbouring ZnII centres are bridged by carboxylate groups in the syn-anti mode to form one-dimensional chains. Adjacent chains are linked through 1,1'-biphenyl-2,2',4,4'-tetracarboxylate and 1,4-bis(1H-imidazol-1-yl)benzene ligands to form a three-dimensional network. In the solid state, the compound exhibits blue photoluminescence and represents a promising candidate for a thermally stable and solvent-resistant blue fluorescent material.