A thermodynamic analysis of refueling of a hydrogen tank☆

Abstract

A thermodynamic analysis of refueling of a gaseous hydrogen fuel tank is described. This study may lend itself to the applications of refueling a hydrogen storage tank onboard a hydrogen fuel-cell vehicle. The gaseous hydrogen is treated as an ideal or a non-ideal gas. The refueling process is analyzed based on adiabatic, isothermal, or diathermal condition of the tank. A constant feed-rate is assumed in the analysis. The thermodynamic state of the feed stream also remains constant during refueling. Ideal-gas assumption results in simple closed-form expressions for tank temperature, pressure, and other parameters. The non-ideal behavior of high-pressure gaseous hydrogen is addressed using the newly developed equation of state for normal hydrogen, which is based on the reduced Helmholtz free energy formulation. Sample calculations are presented using initial tank and feed stream conditions commensurate to practical vehicular applications. Comparing to the non-ideal analysis, the ideal-gas assumption always results in under-prediction of the tank temperature and pressure irrespective of the filling condition. For a given target tank pressure, the refueling time is the shortest under adiabatic condition and is the longest under isothermal condition with the tank being maintained at the initial tank temperature. The adiabatic and isothermal conditions can be viewed, respectively, as the lower and upper bounds of the refueling time for a given final target tank pressure.