Study on the rapid decompression rate of PA6 liner material of type IV on-board hydrogen storage cylinders

Abstract

Investigations were carried out in this paper to study the influence of rapid decompression rate on the polyamide 6 (PA6) liner materials through experimental and numerical methods. Firstly, hydrogen permeation tests at different pressures were conducted to obtain the functions representing the trend of permeation parameters with the pressure. Then decompression tests at different decompression rates had been carried out to get whitening specimens which would be observed using scanning electron microscopy (SEM). Cavitation was found and the variety of the number of cavities with the decompression rate was recorded. It was found that the faster the decompression rate was, the higher the number of cavities in the specimen was. Thirdly, to determine the hydrogen concentration throughout the specimen and numerically check if cavitation occurred at various decompression rates, a 2D finite element model was established which introduced the permeation parameters as functions of pressure but not temperature, as another numerical model indicated the temperature field of specimens changed little. Then an approach was proposed to successfully implement the risk assessment of cavitation, and the liner material was considered as elastoplastic neglecting its viscoelasticity-viscoplasticity. Based on the assumptions and experimental conditions in the study, the Mises yield criterion was successful to assess the cavitation risk, and the approach was verified as the analysis results about the cavitation agree well with the SEM observations. In the end, based on the approach, it could be concluded that 11h was the critical safe decompression time for the PA6 material in this study, and the decompression rate was 7.95 MPa/h. The approach in this study can also be used as guidelines for the cavitation risk assessment of other systems and materials undergoing rapid decompression.