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Abstract
A new photo-responsive tetracationic macrocycle was designed and synthesized by connecting two bis(imidazolium)-tetrachloro-azobenzene units with o-xylene linkers. The ability of red-light triggered photoisomerization of the incorporated tetrachloroazobenzene units has featured this macrocycle with reversible photo-triggered configurational transformation, benefiting from which the distinctive red-light regulated encapsulation behavior for aromatic dicarboxylic dianions in DMSO solution could be achieved.
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