Abstract

AbstractAn efficient system for the synthesis of acetic acid via dehydrogenation of an ethanol–water solution using a new iridium catalyst bearing a functional bipyridonate ligand with N,N‐dimethylamino substituents was developed. Quantitative production of acetic acid from an ethanol–water solution was achieved. In addition, recovery and reuse of the catalyst using a simple procedure was also accomplished. Moreover, this catalytic system can be applied in the dehydrogenative transformation of various primary alcohols to the corresponding carboxylic acids.

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