Abstract
AbstractThe reduction of esters and aldehydes to alcohols is an important reaction in the chemical industry to produce a wide range of bulk and fine chemicals. Herein, the unexpected behavior of three state‐of‐the‐art, commercially available Ru‐catalysts for the hydrogenation of these feedstocks is reported. For ester and aldehydes containing a C=C bond, it was possible to carry out the selective hydrogenation of the ester or aldehyde functionality while keeping the C=C double‐bond essentially untouched. Furthermore, it is demonstrated that these substrates can be reduced under very mild reaction conditions (as low as 40 °C and 5 bar of H2) and that anisole, a solvent with a high sustainability rank, is suitable for these catalytic hydrogenations.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
