A Superhydrophobicity-Slipperiness Switchable Surface with Magneto- and Thermo-responsive Wires for Repelling Complex Droplets.

Abstract

The inefficacy of repelling water droplets laden with macromolecules (complex droplets or diluted polymer solution) is a long-standing shortcoming of superhydrophobic surfaces, which severely limits their reliability in practical applications. Here, we design a surface termed the superhydrophobicity-slipperiness switchable surface (3S surface), which demonstrates superhydrophobicity at room temperature and slipperiness when heated. The 3S surface is composed of magneto-responsive wires coated with superhydrophobic nanoparticles and impregnated with thermoresponsive paraffin, exhibiting lotus leaf-inspired passive water repellency and respiratory cilia-inspired active water repellency at room temperature. When heated, the impregnated paraffin melts and forms a lubricant layer atop the surface structures, exhibiting the pitcher-plant-inspired removal of complex droplets that remain pinned on conventional superhydrophobic surfaces. The counterintuitive integration of superhydrophobicity (a liquid-solid-gas composite system) and slipperiness (a liquid-lubricant-gas system) into a surface and the on-demand switch between them are not only important to the applicability of self-cleaning surfaces to real-world environments, where complex liquids are inevitable, but also provide insights into various interface-related applications.