Abstract
Abstract This study investigated the uniqueness of advancing contact angle (CA) by examining the evaporation process of a sessile drop of surfactant solution [sodium dodecyl sulfate (SDS), hexaethylene glycol monododecyl ether (C12E6) and Triton X-100 (TX-100)] on parafilm. The sessile drop was formed from a pendant drop that had reached its equilibrium surface tension in an atmosphere with ∼100% humidity. The relaxation of the drop profile and wetting diameter were recorded from the moment the drop touched the parafilm, and the data were then analyzed to determine the advancing CA. The results showed that for SDS solution drops, only one advancing CA was observed at each SDS concentration. However, the experimental data of TX-100 and C12E6 solution drops indicated the presence of two distinct regions that showed a near-constant CA with a quasi-equilibrium advance of the triple line; hence matching the definition of an advancing CA. The possibility of the existence of two advancing CA was further explored and the presence of two advancing CA for the sessile drops of TX-100 and C12E6 solution was verified by closely examining the advance of the triple line.
Published Version
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