Abstract

Thepoly-crystallineLa0.5Nd0.15Ca0.35MnO3 has been synthesized by a conventional solid reaction method through the cation doping in LaCaMnO3. The analysis of the powder XRD of the composites revealed the formation of an orthorhombic structure in Pbnm space group. The cell parameters of the formed system has obtained and confirmed through Reitveld analysis and it is found to be a=5.4505,b=5.4457,c=7.6876.The lattice parameters and the spin ordering temperature TC of this system are decreasing due to Nd substitution. The ac and dc magnetization studies and resistivity measurements in ZFC and FC mode gives good understanding to the magnetic and electric transport properties of the doped system. The magnetization studies show a paramagnetic to ferromagnetic transition at a temperature below the critical temperature TC.The resistivity measurements reveals semiconducting to metallic transition below the temperature TMS. The temperature dependent transport nature shown in this system is one type of the correlated polaron hopping mechanism and it can be modeled by an adiabatic small polaron hopping(SPH) mechanism.

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