Abstract

The triplet characteristics of two 7-amino coumarin laser dyes (7-diethylamino 4-methyl coumarin (C 1) and 7-diethylamino 4-trifluoromethyl coumarin (C 1F)) were studied in benzene solution using the nanosecond pulse radiolysis technique. Their T—T absorption spectra, rate constants for triplet to ground state transition and triplet—triplet annihilation and G values were determined. The energy transfers from coumarin triplets to various acceptor molecules such as pyrene, t-stilbene and anthracene and from benzene, biphenyl and naphthalene triplets to these dyes as acceptors were studied. Estimates of their energy levels were made.

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