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https://doi.org/10.1002/recl.19760950108
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Cite Publication Date: Jan 1, 1976 | |
 Citations: 23 |
Affiliation: Utrecht University
Abstract1‐Alkynyl sulfides R1C≡C‐S‐R2 1 are easily converted with a copper(I) hydride complex in tetrahydrofuran into cis‐1‐alkenyl sulfides R1CHCH‐S‐R2 2 in yields >90%. Treatment of compounds 1 with LiAlH4 in the same solvent leads to the isomeric trans‐1‐alkenyl sulfides R1CH CH‐S‐R2 3 in almost quantitative yield.
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