Abstract
AbstractA convergent and stereoselective total synthesis of decarestrictine I, a polyketide natural product, is described. Both acid and alcohol fragments were prepared from the readily available L‐malic acid via StillGennari olefination and Sharpless asymmetric epoxidation. The Steglich esterification and ring‐closing metathesis (RCM) are employed to combine both acid and alcohol fragments.
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