Abstract
A high-yielding and stereocontrolled construction of 2-azido-2-deoxy-1,2- trans-β-glycosidic linkages has been achieved by exploiting TMSOTf-promoted 1,2- trans-glycosidation of 2-azido-2-deoxyglycopyranosyl diphenyl phosphates with various glycoside alcohols in propionitrile at −78°C. The present method exhibits the highest levels of 1,2- trans-β-selectivity reported to date for this type of glycosidation.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
