Abstract

The reaction of nickel(II) nitrate with isonicotinic acid and 2,6-dimethyl-pyridine-3,5-dicarboxylic acid affords a novel, tetranuclear nickel(II)-based metal-organic framework that exhibits spin-canted antiferromagnetism with a canted angle of 1.65° and high adsorptive selectivity for light hydrocarbons.

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