Abstract

B‐trichloroborazene reacts with bis(trimethylsilyl)carbodiimide to form non‐oxide gels (see scheme). The xerogels consist of a polymeric network of borazine rings linked by carbodiimide groups. Pyrolysis at 1200°C provides amorphous ceramics with the composition BC0.23N1.1Si0.05H0.09 ≈ B4CN4. At 2000°C pure B4C is formed.

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