Abstract

AbstractAddition of fluoroalkyl iodides to olefins in the presence of hydrogen peroxide (H2O2) in acetone, acetonitrile or ethanol gave the corresponding 1:1 adducts in good yields. Reaction of fluoroalkyl iodide with diallyl ether (DAE) yielded tetrahydrofuran derivatives. p‐Hydroquinone (p‐HQ) can partly suppress the reaction. A radical initiation mechanism is proposed.

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