Abstract
Introduction of an allyl functionality at C-3 of 1,2:5,6-di- O-isopropylidene-α- d-glucofuranose followed by olefination at C-5 and C-6 provided 1,6-diene 5 which, upon ring closing metathesis and subsequent functional group manipulation, furnished the key cyclopentene diacetate 7, which was elaborated to carbanucleoside (−)-carbovir 1.
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