A Review of Recent Chitosan Anion Exchange Membranes for Polymer Electrolyte Membrane Fuel Cells.

Abstract

Considering the critical energy challenges and the generation of zero-emission anion exchange membrane (AEM) sources, chitosan-based anion exchange membranes have garnered considerable interest in fuel cell applications owing to their various advantages, including their eco-friendly nature, flexibility for structural modification, and improved mechanical, thermal, and chemical stability. The present mini-review highlights the advancements of chitosan-based biodegradable anion exchange membranes for fuel cell applications published between 2015 and 2022. Key points from the rigorous literature evaluation are: grafting with various counterions in addition to crosslinking contributed good conductivity and chemical as well as mechanical stability to the membranes; use of the interpenetrating network as well as layered structures, blending, and modified nanomaterials facilitated a significant reduction in membrane swelling and long-term alkaline stability. The study gives insightful guidance to the industry about replacing Nafion with a low-cost, environmentally friendly membrane source. It is suggested that more attention be given to exploring chitosan-based anion exchange membranes in consideration of effective strategies that focus on durability, as well as optimization of the operational conditions of fuel cells for large-scale applications.