Abstract
A highly sensitive, selective, and well-repeatable optical fiber sensor was proposed for trace measurement of Hg2+ concentration in the water environment based on Mach-Zehnder interference. The proposed structure was prepared by splicing a piece of thin core fiber (TCF) between multimode fibers (MMF) to form MMF-TCF-MMF. A novel sensitive film 3-mercaptopropyl-trimethoxysilane (MPTMS) modified polyvinyl alcohol (PVA) has been designed and synthesized, and uniformly coated on the surface of TCF. The specific combination of Hg2+ with PVA-MPTMS sensitive film can change the effective refractive index of the coating mode, enabling the measurement of Hg2+ concentration by tracking the interference spectra. The results show that the sensitivity of the PVA-MPTMS-coated sensor can achieve 17.5 nm/μM with a detection limit of 3.42 nM in the concentration range of 0–1000 nM. The sensor represents excellent repeatability and stability and a rapid response time of roughly 90 s. Meanwhile, the proposed sensor shows a specific recognition of Hg2+ and is unaffected by many other interfering metal ions in the water, which corresponds well with the binding energy calculated by the density functional theory (DFT). The sensor for Hg2+ detection exhibits compact structure, rapid response, high selectivity and repeatability, showing promising potential applications in the field of environmental monitoring.
Published Version
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