Abstract
A quantitative measure of the extent of conjugation is introduced. The number of Dewar resonance structures (DS) in a conjugated hydrocarbon quantitatively determines its extent of conjugation interaction. The greater the degree of conjugation the more stable is the conjugated hydrocarbon. The number of single bonds joining the exo-double bonds of a purely cross-conjugated hydrocarbon is equal to its number of Dewar resonance structures (DS). Polyene cross-conjugated hydrocarbons are minimally conjugated and possess only one classical structure with a succession of fixed single and exo-double bonds. There are three increasing levels of conjugation for systems with a single classical structure according to whether they are cross-conjugated, linear extended two-way conjugated, and ring-enhanced conjugated. Numerous analytical expressions have been derived. Our valence-bond (VB) approach involves studying the interrelationship of several well-known series of conjugated hydrocarbons having only a single classical structure, i.e., the number of Kekulé resonance structures is one (K = 1). This work provides a totally new perspective to the concept of conjugation.
Published Version
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