Abstract
As a variety of metal-mediated biaryl formations througharomatic C H activation have been popularized, theSuzuki–Miyaura-type reactions, in which aryl halides orpseudohalides are replaced by (hetero)arenes, have recentlyattracted attention. This type of cross-coupling is not onlyan efficient and complementary process to form biaryls, butalso is in connection with sustainable chemistry. Whereasthe Suzuki–Miyaura-type direct C H arylation of arenes(which generally require a directing group) has been devel-oped greatly,
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