Abstract

The polyoxometalate-based 1D coordination polymer [Cu(DMF) 6][PMo VMo VI 11O 40Cu(DMF) 4]·DMF 1 was synthesized and characterized by IR, UV spectroscopy and single-crystal X-ray diffraction analysis. Each Cu(II) center has a distorted octahedral coordination geometry. Cu(1) center interconnects with two [PMo VMo VI 11O 40] 4− anion subunits and each [PMo VMo VI 11O 40] 4− polyoxoanion acts as a didentate ligand to link two Cu centers through two terminal oxygen atoms to form a one-dimensional chain structure. The luminescent properties of 1 in the solution and in the solid state were investigated, respectively.

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