Abstract
A one-dimensional Zn(II) complex [Zn(Im)2(NO2–BDC)]n (1) (Im = Imdazole, NO2–H2BDC = 5-nitro-1,3- benzenedicarboxylic acid) is synthesized and characterized using single crystal X-ray diffraction, IR spectroscopy and elemental analysis. Single crystal X-ray diffraction analysis reveals that complex 1 is a one-dimensional chain polymer with a Zn⋯Zn separation of 9.6190(2) A arranged parallel to the (1 0 0) crystal direction. In addition, the luminescence measurements reveal that complex 1 exhibits strong fluorescent emissions in the solid state at room temperature.
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