A numerical study of CaCO3 deposition on the membrane surface of direct contact membrane distillation

Abstract

This numerical study investigates the effect of CaCO3 deposition on the performance of direct contact membrane distillation (DCMD). It is the first numerical study to directly evaluate the deposition and film thickness of CaCO3 on the membrane surface. Therefore, a 3D computational fluid dynamics (CFD) model, which combines momentum, heat, species transport reaction, and the Eulerian wall film model, is used to analyze the CaCO3 mass deposition rate and scaling deposition thickness on the membrane surface. HSC Chemical Software is used to evaluate the ion compositions and reaction kinetics, including the activation energy (Ea) and pre-exponential factor (Ar). The CFD model is validated with experimental results. The results reveal that the CaCO3 deposition rate increases significantly at a high temperature, velocity, and salinity of the solution. The CaCO3 mass deposition increased by 15 times and scaling deposition thickness increased from 0.05 nm to 1 nm when the temperature was raised from 318.15 K to 348.15 K, whereas an increase of approximately 25 % in deposition was observed with an increase in velocity from 0.17 to 1.38 m/s at a concentration of calcium (Ca+2) ions, 0.03 % and bicarbonate (HCO3−) ions 0.004 %. The results also indicate that CaCO3 deposition decreases the flux and efficiency of the DCMD by 2 % with a low concentration of Ca+2 ions, 0.03 %, and HCO3− ions, 0.004 %. The findings indicate that the high feed salinity (75.23 g/l) increases CaCO3 mass deposition and scaling deposition thickness on the membrane surface due to the high concentration of Ca+2 ions, 0.07 %, and HCO3− ions, 0.01 %, significantly reducing the permeate flux by 14 %. The study's model development and implementation can be adjusted to offer guidance for studying the MD process in treating high saline water with fouling issues.