A novel utilization of raw sepiolite: preparation of magnetic adsorbent directly based on sol-gel for adsorption of Pb(II).

Abstract

The constraints of industrial separation technology for low grade sepiolite greatly limit the development and utilization of these potential resources. In this work, a novel sepiolite adsorbent loaded with copper ferrite was prepared by sol-gel method to remove Pb(II) from wastewater. The effects of various factors on Pb(II) removal ratio were investigated. The maximum adsorption capacities at 293, 313, and 333K were 1285.32, 1325.45, and 1390.54mg/g, respectively. The adsorption of Pb(II) by magnetic sepiolite was a spontaneous endothermic process. Besides, the adsorption process followed Langmuir isothermal adsorption model and pseudo-second-order kinetic model. The main adsorption mechanism of Pb(II) removal was electrostatic attraction, ion exchange, and surface complexation. The improvement of Pb(II) absorption indicated that the efficient removal of Pb(II) can be realized by phosphate groups introduced in the preparation process and the carbonate groups contained in gangue minerals.