A novel star polymer for regulating fluid loss in oil-based mud under high temperature conditions

Abstract

Oil-Based Mud (OBM) is a highly effective drilling fluid system for challenging wellbore conditions such as water-sensitive and high-temperature drilling operations. To minimize filtration loss and achieve thin filter cake, fluid loss control additives are essential. This study introduces a star polymer as an alternative to traditional additives like gilsonite or linear polymer. The star polymer was synthesized using Reversible Addition Fragmentation Chain Transfer polymerization (RAFT) with hydrophilic and lipophilic monomers and crosslinkers. Mud properties such as rheology, fluid loss, mud cake thickness, and emulsion stability were evaluated for OBM and compared with commercially available fluid loss control additives at simulated downhole pressure and temperatures. Spectroscopy and thermogravimetric analysis were used to determine the chemical architecture and thermal stability of the star polymer. The results showed that the star polymer demonstrated thermal stability up to 225 °C, resulting in a small amount of fluid loss volume and ultra-thin filter cake for OBM systems with mud weight at 10.5 ppg and 13.4 ppg. Furthermore, the star polymer improved emulsion stability without significantly affecting plastic viscosity (PV), unlike commercially available fluid loss control additives. The results were consistent for both diesel and synthetic oil-based mud systems.